October 2015, № 10 (185)

Makarow A.G., Razdobreev D.A., Sagida M.O. THE EFFECT OF TEMPERATURE ON THE SENSITIVITY OF IRON DITELLURIDE ELECTRODE TO ION H₃O⁺Influence of temperature on ability of iron ditelluride electrode to feel change of concentration of ion H₃O⁺ in solution on the example of acid-base electrometric titration with use of a glass electrode as a standard for measurement of рН, is investigated. Dependences of potential of a ditelluride of iron from рН are constructed and coefficients of an inclination of linear sites in the range of temperatures from 20 to 60 °C are calculated. Influence of temperature (in the specified range) on reversibility of electrode process at consecutive change рН from sour (2–2,5 рН) to alkaline (10–11 рН) areas and back is investigated. It is noted, that divergences between two branches of titration increase (towards increase of values рН) from 20 to 40 °C, and then to 60 °C considerably decrease. From the point of view of reversibility of electrode process, the best results were received at 20, 55 and 60 °C. Existence of an alkaline mistake of iron ditelluride electrode at value рН more than 10.5. Differential curves titration are constructed at various temperatures, and correlation of the received peaks with indicators of constants of ionization of the acids, which are a part of titrable mix (acetic, phosphoric, boric acids), is executed. The studied electrode on a basis of a ditelluride of iron, unlike traditionally used glass electrode, doesn't demand application of a thermal compensator for measurement рН at various temperatures, and also possesses quite inert surface which isn't losing mirror gloss at contact with sour or alkaline solutions, water and air for a long time.Key words: iron ditelluride, electrometric titration, indicator electrodes.

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References:

1 Measurements in industry: Ref. ed. in 3 books. Book 3. Methods of measurement and instrumentation: trans. with germ. / Under the editorship of Profos P. — 2nd ed., rev. and add. — M.: Metallurgy, 1990. 344 s.

2 Makarow, A.G., Razdobreev, D.A., Sagida, M.O. Sensors pH on the basis chalcogenides of iron // Vestnik OSU, Orenburg. — 2014. — №6(167). — P. 224-228.

3 Budnikov, G.K. Foundations of modern electrochemical analysis — М.: Peace: Binom LZ, 2003. — 592 p., il.

4 Lurie, Y.Y. Handbook on analytical chemistry. — M.: Chemistry, 1971. — 456 P.

5 Chukhrov, F. V. Minerals. Guide / F. V. Chukhrov, E. M. Bonstedt-Kupletskaya. — M.: Publishing house of the USSR Academy of Sciences. — 1960. — Vol. 1. — 538 S.

About this article

Authors: Makarov A.G., Razdobreev D.A., Sagida M.O.

Year: 2015

Editor-in-chief

Sergey Aleksandrovich
MIROSHNIKOV

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