November 2015, № 13 (188)

Rusinov A.P., Kucherenko M.G. INFLUENCE OF SILVER NANOPARTICLES ON THE OPTICAL ABSORPTION SPECTRA OF ORGANIC DYES MOLECULES IN POLYMER SOLUTIONS AND MEMBRANESObjects and systems structured at the nanometer scale are of great interest among researchers due to the presence of their specific physical properties. Due to considerable experimental difficulties and limitations of theoretical approaches, the focus now is on study of relatively simple nano-objects for which there are suitable experimental methods, known methods of synthesis and physical models for theoretical description of their properties. As an example of such a system is considered colloidal solutions of metal nanoparticles and nanoparticles in polymer film. Influence of metal nanoparticles on molecular environment due to the presence of plasmon oscillations of electron gas density. This changes the interaction efficiency between nearby molecules with external electromagnetic field and the rate of photoinduced processes in this area. The influence of various concentrations of silver nanoparticles on absorption spectra of organic dyes molecules in water solutions and thin polyvinyl alcohol films is investigated. It is found that with increasing concentration of metal nanoparticles optical density of polymer solutions and films in the 380–450 nm band increases monotonically, as in the 490–570 nm band increases at low nanoparticles concentrations and decreases at higher nanoparticles concentrations. Maximum enhancement of the dye absorption is observed when at concentration nanoparticles near 10-9 M. Based on the model of influence metal nanoparticles on interaction of organic dye molecules with linearly polarized monochromatic electromagnetic field spatial orientation and frequency dependence of transition probabilities in dye molecule within nanoparticles is calculated. It is shown a qualitative agreement between the theoretical frequency dependences with the experimental results of concentration effect of silver nanoparticles on the absorption intensity of dye molecules in different spectral ranges.Key words: silver nanoparticle, organic dye, absorption spectrum, induced transitions.

Download

References:

1. Klimov V. V. Nanoplasmonics. Moscow. Fizmatlit. 2009.  — 480 p.

2. A. Delga, J. Feist, J. Bravo-Abad and F.J. Garcia-Vidal Theory of strong coupling between quantum emitters and localized surface plasmons. // Journal of Optics.  — 2014.  — V.16,  — 114018 (8 pp).

3. Pomogaylo A.D., Rozenberg A.S., Uflyand I.E. Nanoparticles of metals in polymers. M.: Chemistry, 2000.  — 672 p.

4. Kosobukin V.A. Anisotropic local field effects in plasmonic nanoparticles optics and magnetooptics. // Fizika tverdogo tela.  — 2012.  — No. 12. T. 54. S. 2340-2348.

5. Zeynidenov A.K., Ibrayev N.K., Kucherenko M.G. Influence of silver nanoparticles on electronic transitions in dyes molecules and generation characteristics of the liquid lasers on their basis. // Vestnik OSU.  — 2014.  — No. 9. T. 170, Pp. 96-102.

6. Suvorova T.I., Balbekova A.N., Klyuev V.G., et.al. Enhancement of luminescence of dye molecules in the presence of silver nanoparticles. // Optichesky journal. 2012.  — T. 79.  — No. 1. — S. 79-82.

7. Long-De Wang, Tong Zhang, Xiao-Yang Zhang et.al. Optical properties of Ag nanoparticle-polymer composite film based on two-dimensional Au nanoparticle array film. // Nanoscale Research Letters.  — 2014.  — №9, P. 155.

8. Solomon S.D. et.al. Synthesis and Study of Silver Nanoparticles. // Journal of Chemical Education.  — 2007.  — Vol. 84.  — №2.  — P. 322–324.

9. Porel S., Venkatram N., Narayana Rao D., Radhakrishnan T.P. In situ synthesis of metal nanoparticles in polymer matrix and optical limiting. // Application Journal of Nanoscience and Nanotechnology.  — 2007.  — Vol.7.  — P. 1–6.

10. Suzdalev I. P. Nanotechnology: physics and chemistry of nanoclusters, nanostructures and nanomaterials.  — M.: Komkniga , 2006.  — 592 p.

11. Rogach A.L., Haluk V.N., Gurin, V.S., Formation of highly dispersed silver in the Ag+ ions in aqueous solutions. // Colloid journal.  — 1994.  — T. 56.  — No. 12.  — P. 276-278.

12. Khlebtsov N.G., Mel'nikov A.G., Bogatyrev V.A. et.al. // J. Phys. Chem. B. — 2005.  — V. 109.  — P. 13578.

13. Krutyakov Yu.A., Kudrinsky A.A, Olenin A.Yu., et.al. Synthesis and properties of nanoparticles. // Uspehi himii.  — 2008.  — No. 77. Vol. 3, Pp. 242-269.

14. Klyshko, D. N. Physical foundations of quantum electronics: Textbook.  — M.: Nauka. 1986.  — 296 p.

15. Landau L.D., Lifshitz E.M. Quantum Electrodynamics. Vol. IV. Moscow: Nauka. 1989.  — 728 p.

16. Landau L.D., Lifshitz E.M. Electrodynamics of Continuous Media. Vol. VIII. Moscow: FIZMATLIT. 2003.  — 656 p.

About this article

Authors: Rusinov A.P., Kucherenko M.G.

Year: 2015

Editor-in-chief

Sergey Aleksandrovich
MIROSHNIKOV

© Электронное периодическое издание: ВЕСТНИК ОГУ on-line (VESTNIK OSU on-line), ISSN on-line 1814-6465
Зарегистрировано в Федеральной службе по надзору в сфере связи, информационных технологий и массовых коммуникаций
Свидетельство о регистрации СМИ: Эл № ФС77-37678 от 29 сентября 2009 г.
Учредитель: Оренбургский государственный университет (ОГУ)
Главный редактор: С.А. Мирошников
Адрес редакции: 460018, г. Оренбург, проспект Победы, д. 13, к. 2335
Тел./факс: (3532)37-27-78 E-mail: vestnik@mail.osu.ru