Tkacheva T.A., Salikova A.N.
RECEIVING, ESTABLISHMENT OF STRUCTURE AND DETERMINATION OF THE ETILENDIAMINOV SPECTROSCOPIC PROPERTIES OF THE S DIPIRIDOHINOKSALINOM CO (II) AND NI (II) COMPLEXES ^{[№ 10 ' 2015]}
Complex transition metal compounds are of interest as systems with directional charge transfer and energy. It is known that the d-elements such as palladium and platinum to form such compounds. For the first time metal chelate compounds of Co (II) and Ni (II) with dipiridohinoksalinom of interest for further research. Improved previously known methods for the synthesis of ligands and metal complexes thereof. The physical parameters of ethylenediamine complexes of Co (II) and Ni (II) with dipiridohinoksalinom. Low temperature melting intervals confirm purity of compounds obtained. Information on the solubility of the compounds needed for further research. IR spectroscopy is informative enough to establish the structure of the compounds obtained, finding connections and functional groups in their structure. Confirmed structure of the synthesized compounds. Changes in the set of functional groups by complexation. The optical properties of the substances. Comparison of the absorption spectra of the free ligands and metal complexes indicates that complexation leads to a shift of the maxima in the spectrum at longer wavelengths (bathochromic shift). Type is set to electronic transitions in accordance with the Koopmans theorem. It is shown that electronic transitions of the metal-ligand absent.

Tkacheva T.A.
RECEIVING AND REVIEW OF THE SPECTROSCOPIC PROPERTIES OF CARBONYL CONTAINING COMPLEXES NI (II) AND CO (II) ^{[№ 10 ' 2013]}
In this article is considered the possibility of using metal-carbonyl compounds as systems with directional charge transfer and energy transfer. Are presented the methods of synthesis of carbonyl-containing compounds based on Co (II) and Ni (II). Are determined by the physicochemical properties of the compounds using potentiometric methods and the structure of the substances with using IR and UV spectroscopy.

Tkacheva N.V., Bobb T.
ESSENCE AND MEANING OF PRINCIPALS OF CRIMINAL PROCEDURE AND THEIR FEATURES ^{[№ 3 ' 2008]}
Essence and meaning of principals of criminal procedure for achievement of criminal legal procedure purpose are regarded in this work.

Tkacheva N.V.
LIMITS OF COMPULSION USE IN CRIMINAL LEGAL PROCEEDING ^{[№ 3 ' 2005]}
Measures of criminal procedural compulsion, used by state bodies and officers as a type of influence on behavior of criminal case participants are regarded in this article.

Tkachyev A.N., Bezrodnij O.K.
EFFECTIVE SERVICE OF THE REGION'S AUTOMOBILE NETWORK ^{[№ 6 ' 2004]}
The principles and the model of automobile network service charge cut-back are proposed. On the basis of these principles and logical conception the approach and the model of structural transformation effectiveness estimate in road management logistic system is eleborated.